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November 17, 2013

The Kramers-Kronig relations - part 1

[See part 2 for some technical aspects]
Very nice derivation of the Kramers-Kronig relations (on Wikipedia, of all places), exploiting the relation between the even and odd components of a function χ(t) and the real and imaginary parts of its Fourier transform χ(ω)=χ(ω)+iχ(ω).

One usually invokes the analyticity of χ(ω) in the upper half-plane, which must first be derived from the causality: χ(t)=0 for t<0. Complex integration along a well-chosen contour then yields the Kramers-Kronig relations in their standard form [1]:
χ(ω)=1iπPdωχ(ω)ωωor, for the components:χ(ω)=1πPdωχ(ω)ωωχ(ω)=1πPdωχ(ω)ωω
where P denotes Cauchy's principal value.
However, this requires two trips to the complex plane and the result is not very intuitive. It is better to split the reasoning into two steps: write the relation in the time domain and then go to the frequency domain by using general (and hopefully, already known) properties of the Fourier transform [2]. This can help separate the conceptual novelty from the technical difficulty.

Illustration of the Kramers-Kronig relations between a physical (i. e. causal and real) signal and its Fourier transform. Work by FDominec, released under a Creative Commons Attribution-Share Alike 3.0 Unported license.
The first step is writing the response function as the sum of its even and odd components:
χ(t)=χe(t)+χo(t)where:χe(t)=12(χ(t)+χ(t))andχo(t)=12(χ(t)χ(t))
 something we can do for any real function. The causality relation (χ(t)=0 for t<0) implies that:
χe(t)=sgn(t)χo(t)andχo(t)=sgn(t)χe(t)
where sgn(t) gives the sign of its argument (-1 for negative and +1 for positive values.)

This is interesting because the real and imaginary parts of the Fourier transform F are given by the even and odd components of the function, respectively:
χ(ω)=χ(ω)+iχ(ω)=F[χ(t)]χ(ω)=F[χe(t)]iχ(ω)=F[χo(t)]
The first step is over; to obtain (???) we must now combine (3) with (???) and go to the frequency domain. We need to remember that the Fourier transform of a product is the convolution of the Fourier transforms of the factors and we also need an expression for the Fourier transform of the sgn(t) function. We will do this in part 2.

[1] P. M. Chaikin and T. C. Lubensky, Principles of condensed matter physics, Cambridge University Press (2000). Chapter 7.
[2] For a recent and readily available reference, see: C. Warwick, Understanding the Kramers-Kronig Relation Using A Pictorial Proof. The idea goes at least as far back as the (very terse) presentation of B. Y.-K. Hu, Kramers-Kronig in two lines, Am. J. Phys. 57, 821, (1989).  ↩

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