Publications

Book chapters

(with Anne-Florence Bitbol et Jean-Baptiste Fournier)
Membrane-Mediated Interactions in
Physics of Biological Membranes
edited by Patricia Bassereau and Pierre Sens, Springer International Publishing, 2018. ISBN 978-3-030-00630-3

This chapter gives an overview of the topic and of our theoretical and experimental work.

Topological evolution in the ordered and isotropic phases of a lyotropic system in
Phase Transitions. Applications in Liquid Crystals, Organic Electronic and Optoelectronic Fields
edited by Vlad Popa-Nita, Research Signpost, Kerala, India, 2006. ISBN 81-308-0062-4

This chapter presents a succinct review of my PhD research. The full text of my PhD thesis (in French) is available here.

Habilitation

Doped lamellar phases

Journal papers

  1. Depletion-Induced Tunable Assembly of Complementary Platonic Solids
    Rahul Nag et al., Nano Letters, ASAP Article (2024).
  2. Prismatic Confinement Induces Tunable Orientation in Plasmonic Supercrystals
    Wajdi Chaâbani et al., ACS Nano, 18, 9566-9575 (2024).
    CNRS Highlight (Chemistry department)
  3. Out-of-Equilibrium Mechanical Disruption of Β-Amyloid-Like Fibers using Light-Driven Molecular Motors
    Dania Daou et al., Advanced Materials, 36, 2311293 (2024). 
    CNRS Highlight (Chemistry department)
  4. Molecular Actuation of a Bistable Liquid-Crystalline [c2]Daisy Chain Rotaxane
    Christian C. Carmona-Vargas et al., ChemistryEurope, 2, e202300069 (2024).
    COVER
  5. Shedding Light on the Birth of Hybrid Perovskites: A Correlative Study by In Situ Electron Microscopy and Synchrotron-Based X-ray Scattering
    Charles Sidhoum et al., Chemistry of Materials, 19, 7943-7956 (2023).
    COVER    SOLEIL Highlight
  6. Confinement Effects on the Structure of Entropy-Induced Supercrystals
    Claire Goldmann et al., Small, 19, 2303380 (2023).
    preprint
  7. Tailoring the 3D porous structure of conducting PEDOT:PSS gels via ice-templating
    Quentin Weinbach et al., Journal of Materials Chemistry C, 11, 7802-7816 (2023).
    preprint
  8. Polymorphous Packing of Pentagonal Nanoprisms
    Jules Marcone et al., Nano Letters, 23, 1337-1342 (2023).
    preprint
  9. Extracting the morphology of gold bipyramids from small-angle X-ray scattering experiments via form factor modelling
    Jieli Lyu et al., Journal of Applied Crystallography, 56, 214-221 (2023).
    preprint
  10. Formation of kinetically trapped small clusters of PEGylated gold nanoparticles revealed by the combination of small-angle X-ray scattering and visible light spectroscopy
    Dániel Szekrényes et al., Soft Matter, 18, 8295-8301 (2022).
    preprint
  11. Longitudinal and Transversal Directed Overgrowth of Pentatwinned Silver Nanorods with Tunable Optical Properties
    Claire Goldmann et al., J. Phys. Chem. C, 126, 11667-11673 (2022).
    preprint
  12. Shape-Controlled Second-Harmonic Scattering from Gold Nanotetrapods
    Jieli Lyu et al., J. Phys. Chem. C, 126, 9831-9835 (2022).
    preprint
  13. Acoustic Vibration Modes of Gold–Silver Core–Shell Nanoparticles
    Tadele Orbula Otomalo et al., Chemosensors, 10, 193 (2022).
    FREE ACCESS    preprint
  14. Unique orientation of 1D and 2D nanoparticle arrays confined in smectic topological defects
    Haifa Jeridi et al., Soft Matter,, 18, 4792 (2022).
    preprint
  15. Efficient Control of a Mesoporous Fibrillar PEDOT:PSS Aerogel Structure for Promising Thermoelectric Applications
    Quentin Weinbach et al., Frontiers in Electronic Materials, 2, 875856 (2022).
    FREE ACCESS    preprint
  16. Double-Lattice Packing of Pentagonal Gold Bipyramids in Supercrystals with Triclinic Symmetry
    Jieli Lyu et al., Advanced Materials, 34, 2200883 (2022).
    preprint    CNRS Highlight (INP department)    SOLEIL Highlight
  17. Versailles project on advanced materials and standards (VAMAS) interlaboratory study on measuring the number concentration of colloidal gold nanoparticles
    Caterina Minelli et al., Nanoscale, 11, 031012 (2022).
  18. Fréedericksz-Like Transition in a Biaxial Smectic-A Phase
    Claire Meyer et al., Phys. Rev. X, 11, 031012 (2021).
    FREE ACCESS    Focus story
  19. Softness-driven complexity in supercrystals of gold nanoparticles
    Brigitte Pansu et al., Soft Matter, 17, 6461 (2021).
    preprint
  20. Symmetry Breaking in Seed-Mediated Silver Nanorod Growth Induced by Dimethyl Sulfoxide
    Claire Goldmann et al., Chem. Mater, 33, 2948-2956 (2021).
    preprint
  21. Structure and Formation Kinetics of Millimeter-Size Single Domain Supercrystals
    Daniel García-Lojo et al., Adv. Func. Mat., 31, 2101869 (2021).
    preprint    CNRS Highlight (INP department)
  22. Doxorubicin-Loaded Metal-Organic Frameworks Nanoparticles with Engineered Cyclodextrin Coatings: Insights on Drug Location by Solid State NMR Spectroscopy
    Xue Li et al., Nanomaterials, 11, 945 (2021).
    preprint
  23. Sharp Spectral Variations of the Ultrafast Transient Light Extinction by Bimetallic Nanoparticles in the Near-UV
    Tadele Orbula Otomalo et al., Adv. Opt. Mat., 9, 2001778 (2021).
    preprint
  24. Interplay of Structure and Dynamics in Lithium/Ionic Liquid Electrolytes: Experiment and Molecular Simulation
    P. Judeinstein et al., J. Phys. Chem. B, 125, 1618-1631 (2021).
    preprint
  25. Two-step assembly kinetics of gold nanoparticles
    Jieli Lyu, Damien Alloyeau, Cyrille Hamon and Doru Constantin, J. Mater. Chem. C, 9, 1730-1739 (2021).
    preprint
  26. Growth Kinetics of Core–Shell Au/Ag Nanoparticles
    Cyrille Hamon and Doru Constantin, J. Phys. Chem. C, 124, 21717-21721 (2020).
    preprint
  27. Determining the morphology and concentration of core–shell Au/Ag nanoparticles
    J. Lyu et al., Nanoscale Advances, 2, 4522-4528 (2020).
    OPEN ACCESS  HOT Article
  28. Grazing Incidence X-ray Diffraction Studies of Lipid–Peptide Mixed Monolayers during Shear Flow
    P. K. Bera et al., ACS Omega, 5, 14555 (2020).
    preprint
  29. Real-Time In Situ Observations Reveal a Double Role for Ascorbic Acid in the Anisotropic Growth of Silver on Gold
    K. Aliyah et al., J. Phys. Chem. Lett., 11, 2830 (2020).
    preprint
  30. From Chains to Monolayers : Nanoparticle Assembly Driven by Smectic Topological Defects
    Syou-P’heng Do et al., Nano Letters 20, 1598 (2020).
    preprint
  31. Interactions between Topological Defects and Nanoparticles
    Syou-P’heng Do et al., Frontiers in Physics 7, 234 (2020).
    preprint
  32. Plasmonic Oligomers with Tunable Conductive Nanojunctions
    Xiaoyan Li et al., J. Phys. Chem. Lett. 10, 7093-7099 (2019).
    preprint.
  33. Insights into the Formation Mechanism of CdSe Nanoplatelets Using in Situ X-ray Scattering
    N. Castro, C. Bouet, S. Ithurria, N. Lequeux, D. Constantin, P. Levitz, D. Pontoni, B. Abécassis, Nano Letters 19, 6466 (2019).
    preprint
  34. Design of Engineered Cyclodextrin Derivatives for Spontaneous Coating of Highly Porous Metal-Organic Framework Nanoparticles in Aqueous Media
    G. Cutrone et al., Nanomaterials 9, 1103 (2019).
  35. Interaction and structuration of membrane-binding and membrane-excluding colloidal particles in lamellar phases
    R. Zakine, D. de Silva Edirimuni, D. Constantin, P. Galatola and J.-B. Fournier, Soft Matter 15, 4351 (2019).
    preprint
  36. Nanoparticle-Templated Self-Assembly of Viral Capsids Probed by Time-Resolved Absorbance Spectroscopy and X-Ray Scattering
    A. Burke, M. Chevreuil, A. Paris, V. de La Grange, C. Goldmann, J. Pérez, D. Constantin, and G. Tresset, Phys. Rev. Applied 10, 054065 (2018).
    preprint
  37. Controlling the symmetry of supercrystals formed by plasmonic core-shell nanorods with tunable cross-section.
    C. Hamon, C. Goldmann and D. Constantin, Nanoscale 10, 18362-18369 (2018).
    preprint
  38. Nonequilibrium self-assembly dynamics of icosahedral viral capsids packaging genome or polyelectrolyte
    M. Chevreuil et al., Nature Comm. 9, 3071 (2018).
    preprint     CNRS Highlight (INP department)
  39. Direct Liquid to Crystal Transition in a Quasi-Two-Dimensional Colloidal Membrane
    T. Gibaud and D. Constantin, J. Phys. Chem. Lett. 9, 4302-4307 (2018).
    preprint
  40. Isotropic, nematic, and lamellar phases in colloidal suspensions of nanosheets
    P. Davidson, C. Penisson, D. Constantin, and J.-C. P. Gabriel, Proc. Natl. Acad. Sci 115, 6662-6667 (2018).
    OPEN ACCESS
  41. The effect of gramicidin inclusions on the local order of membrane components
    E. Azar, D. Constantin, D. E. Warschawski, European Physical Journal E 41, 44 (2018).
    preprint
  42. Coupling between Inclusions and Membranes at the Nanoscale
    F. Bories, D. Constantin, P. Galatola, J.-B. Fournier, Phys. Rev. Lett. 120, 128104 (2018).
    preprint    CNRS Highlight (INSIS department)
  43. Reversible strain alignment and reshuffling of nanoplatelet stacks confined in a lamellar block copolymer matrix
    Emmanuel Beaudoin, Patrick Davidson, Benjamin Abecassis, Thomas Bizien and Doru Constantin, Nanoscale, 9, 17371 (2017).
  44. Ionic Liquids: evidence of the viscosity scale-dependence
    Quentin Berrod, Filippo Ferdeghini, Jean-Marc Zanotti, Patrick Judeinstein, Didier Lairez, Victoria Garcia Sakai, Orsolya Czakkel, Peter Fouquet and Doru Constantin, Scientific Reports, 7, 2241 (2017).
    preprint     ILL News 2017
  45. Nanostructuration of Ionic Liquids: impact on the cation mobility. A multi-scale study.
    Filippo Ferdeghini, Quentin Berrod, Jean-Marc Zanotti, Patrick Judeinstein, Victoria Garcia Sakai, Orsolya Czakkel, Peter Fouquet and Doru Constantin, Nanoscale, 9, 1901-1908 (2016).
    preprint
  46. Solution Self-Assembly of Plasmonic Janus Nanoparticles
    N. Castro, D. Constantin, P. Davidson and B. Abécassis, Soft Matter 12, 9666-9673 (2016).
    preprint
  47. Identification of a major intermediate along the self-assembly pathway of an icosahedral viral capsid by using an analytical model of a spherical patch
    D. Law-Hine, M. Zeghal, S. Bressanelli, D. Constantin and G. Tresset, Soft Matter 12, 6728-6736 (2016).
    preprint
  48. Solution scattering from colloidal curved plates: barrel tiles, scrolls and spherical patches
    Doru Constantin, J. Appl. Cryst. 48, 1901 (2015).
    preprint
  49. Why the aspect ratio? Shape equivalence for the extinction spectra of gold nanoparticles
    Doru Constantin, Eur. Phys. J. E 38, 116 (2015).
    preprint
  50. Varying the counter ion changes the kinetics, but not the final structure of colloidal gels
    L. Zhang et al., J. Coll. Interf. Sci. 463, 137-144 (2015).
  51. Reconstruction of the Disassembly Pathway of an Icosahedral Viral Capsid and Shape Determination of Two Successive Intermediates
    D. Law-Hine, A. K. Sahoo, V. Bailleux, M. Zeghal, S. Prevost, P. K. Maiti, S. Bressanelli, D. Constantin, and G. Tresset, J. Phys. Chem. Letters 6, 3471-3476 (2015).
    preprint
  52. Real-Time in Situ Probing of High-Temperature Quantum Dots Solution Synthesis
    B. Abécassis, C. Bouet, C. Garnero, D. Constantin, N. Lequeux, S. Ithurria, B. Dubertret, B. R. Pauw, and D. Pontoni, Nano Letters 15, 2620-2626 (2015).
    preprint     ESRF Highlights 2015
  53. Strain-controlled fluorescence polarization in a CdSe nanoplatelet–block copolymer composite
    E. Beaudoin, B. Abécassis, D. Constantin, J. Degrouard and P. Davidson, Chemical Communications 51, 4051-4054 (2015).
  54. Morphology of gold nanoparticles determined by full-curve fitting of the light absorption spectrum. Comparison with X-ray scattering and electron microscopy data
    K. Slyusarenko, B. Abécassis, P. Davidson and D. Constantin, Nanoscale 6, 13527-13534 (2014).
    preprint
  55. Infrared dichroism of gold nanorods controlled using a magnetically addressable mesophase
    K. Slyusarenko, D. Constantin, B. Abécassis, P. Davidson and C. Chanéac, J. Mater. Chem. C 2, 5087-5092 (2014).
    preprint
  56. A two-dimensional nematic phase of magnetic nanorods
    K. Slyusarenko, D. Constantin and P. Davidson, J. Chem. Phys. 140, 104904 (2014).
    preprint
  57. Lamellar Lα mesophases doped with inorganic nanoparticles
    D. Constantin and P. Davidson, ChemPhysChem 15, 1270-1282 (2014).
    preprint
  58. Hybrid nanocomposites with tunable alignment of the magnetic nanorod filler
    F. Perineau, C. Rosticher, L. Rozes, C. Chaneac, C. Sanchez, D. Constantin, I. Dozov, P. Davidson, and C. Rochas, ACS Appl. Mater. Interfaces 6, 1583-1588 (2014).
    preprint
  59. The amine content of PEGylated chitosan Bombyx mori nanoparticles acts as a trigger for protein delivery
    D. Vasquez, R. Milusheva, P. Baumann, D. Constantin, M. Chami, and C. G. Palivan, Langmuir 30, 965-975 (2014).
  60. Norovirus Capsid Proteins Self-Assemble through Biphasic Kinetics via Long-Lived Stave-like Intermediates
    Guillaume Tresset, Clémence Le Coeur, Jean-François Bryche, Mouna Tatou, Mehdi Zeghal, Annie Charpilienne, Didier Poncet, Doru Constantin, and Stéphane Bressanelli, J. Am. Chem. Soc. 135, 15373–15381 (2013).
    Cover   JACS Spotlights   ESRF Highlights 2013
  61. Smectic mesophases of functionalized silver and gold nanoparticles with anisotropic plasmonic properties
    W. Lewandowski, D. Constantin, K Walicka, D. Pociecha, J. Mieczkowski, and E. Górecka, Chemical Communications 49, 7845–7847 (2013).
  62. Structure, thermodynamics and dynamics of the isotropic phase of spherical non-ionic surfactant micelles
    Kévin Tse-Ve-Koon, Nicolas Tremblay, Doru Constantin, and Éric Freyssingeas, Journal of Colloid and Interface Science 393, 161–173 (2013).
  63. Bilayer Elasticity at the Nanoscale: The Need for New Terms
    Anne-Florence Bitbol, Doru Constantin, and Jean-Baptiste Fournier, PLOS One 7, e48306 (2012).
    OPEN ACCESS
  64. The interaction of charged nanoparticles at interfaces
    Andreas S. Poulos, Doru Constantin, Patrick Davidson, Marianne Impéror-Clerc, Brigitte Pansu, and Stéphan Rouzière, EPL 100, 18002 (2012).
    preprint
  65. Insertion of Gold Nanoparticles in Fluid Mesophases: Size Filtering and Control of Interactions
    Brigitte Pansu, Amélie Lecchi, Doru Constantin, Marianne Impéror-Clerc, Michèle Veber, and Ivan Dozov, The Journal of Physical Chemistry C 115, 17682–17687 (2011).
  66. Slow dynamics of a colloidal lamellar phase
    Doru Constantin, Patrick Davidson, Éric Freyssingeas, and Anders Madsen, The Journal of Chemical Physics 133, 224902 (2010).
    preprint
  67. The interaction of hybrid nanoparticles inserted within surfactant bilayers
    Doru Constantin, The Journal of Chemical Physics 133, 144901 (2010).
    preprint
  68. Short-range dynamics of a nematic liquid-crystalline phase
    Andreas S. Poulos, Doru Constantin, Patrick Davidson, Brigitte Pansu, Eric Freyssingeas, Anders Madsen and Corinne Chanéac, The Journal of Chemical Physics 132, 091101 (2010).
    preprint    ESRF Highlights 2010
  69. Lyotropic Lamellar Phase Doped with a Nematic Phase of Magnetic Nanorods
    Doru Constantin, Patrick Davidson, and Corinne Chanéac, Langmuir 26, 4586-4589 (2010).
    preprint
  70. A PGSE-NMR Study of Molecular Self-Diffusion in Lamellar Phases Doped with Polyoxometalates
    Andreas S. Poulos, Doru Constantin, Patrick Davidson, Marianne Impéror, Patrick Judeinstein and Brigitte Pansu, The Journal of Physical Chemistry B 114, 220-227 (2010).
    preprint
  71. Membrane-mediated repulsion between gramicidin pores
    Doru Constantin, Biochimica et Biophysica Acta (BBA) - Biomembranes 1788, 1782-1789 (2009).
    preprint
  72. Intermittent Brownian dynamics over a rigid strand: Heavily tailed relocation statistics in a simple geometry
    Pierre Levitz, Michel Zinsmeister, Patrick Davidson, Doru Constantin, and Olivier Poncelet, Physical Review E 78 030102(R) (2008).
  73. Repulsion Between Inorganic Particles Inserted Within Surfactant Bilayers
    Doru Constantin, Brigitte Pansu, Marianne Impéror, Patrick Davidson, and François Ribot, Physical Review Letters 101, 098101 (2008).
    preprint
  74. Magnetic Nanorods Confined in a Lamellar Lyotropic Phase
    Keevin Béneut, Doru Constantin, Patrick Davidson, Arnaud Dessombz, and Corinne Chanéac, Langmuir 24, 8205–8209 (2008).
    preprint
  75. Photochromic Hybrid Organic-Inorganic Liquid-Crystalline Materials Built from Nonionic Surfactants and Polyoxometalates: Elaboration and Structural Study
    Andreas S. Poulos, Doru Constantin, Patrick Davidson, Marianne Impéror, Brigitte Pansu, Pierre Panine, Lionel Nicole, and Clément Sanchez, Langmuir 24, 6285–6291 (2008).
    preprint
  76. Interaction of Alamethicin Pores in DMPC Bilayers
    Doru Constantin, Guillaume Brotons, Ansgar Jarre, Chenghao Li, and Tim Salditt, Biophysical Journal 92, 3978–3987 (2007).
    preprint
  77. Dynamics of bulk fluctuations in a lamellar phase studied by coherent x-ray scattering
    Doru Constantin, Guillaume Brotons, Tim Salditt, Eric Freyssingeas, and Anders Madsen, Physical Review E 74, 031706 (2006).
    preprint    ESRF Highlights 2006
  78. Structure and interaction potentials in solid-supported lipid membranes studied by X-ray reflectivity at varied osmotic pressure
    Ulrike Mennicke, Doru Constantin, and Tim Salditt, European Physical Journal E 20, 221–230 (2006).
    preprint
  79. Electric field unbinding of solid-supported lipid multilayers
    Doru Constantin, Christoph Ollinger, Michael Vogel, and Tim Salditt, European Physical Journal E 18, 273–278 (2005).
    preprint
  80. Lipid membranes on a surface grating studied by neutron reflectometry
    Christoph Ollinger, Doru Constantin, Jens Seeger, and Tim Salditt, Europhysics Letters 71, 311–317 (2005).
    preprint
  81. Biomimetic membranes of lipid-peptide model systems prepared on solid support
    Chenghao Li, Doru Constantin, and Tim Salditt, Journal of Physics Condensed Matter 16, S2439-S2453 (2004).
    preprint
  82. Solid-Supported Lipid Multilayers : Structure Factor and Fluctuations
    Doru Constantin, Ulrike Mennicke, Chenghao Li, and Tim Salditt, European Physical Journal E 12, 283-290 (2003).
    preprint
  83. Comment on "Tracer diffusion in a dislocated lamellar system"
    Doru Constantin and Robert Hołyst, Physical Review Letters 91, 039801 (2003).
    preprint
  84. Structural transition in the isotropic phase of the C12EO6/H2O lyotropic mixture : A rheological investigation
    Doru Constantin, Eric Freyssingeas, Jean-François Palierne, and Patrick Oswald, Langmuir 19, 2554-2559 (2003).
    preprint
  85. High-frequency behaviour of an isotropic and multiconnected surfactant phase
    Doru Constantin, Jean-François Palierne, Eric Freyssingeas, and Patrick Oswald, Europhysics Letters 58, 236-242 (2002).
    preprint
  86. Connectivity of the Hexagonal, Cubic, and Isotropic Phases of the C12EO6/H2O Lyotropic Mixture Investigated by Tracer Diffusion and X-ray Scattering
    Doru Constantin, Patrick Oswald, Marianne Impéror-Clerc, Patrick Davidson, and Paul Sotta, The Journal of Physical Chemistry B 105, 668-673 (2001).
    preprint
  87. Diffusion coefficients in a lamellar lyotropic phase: evidence for defects connecting the surfactant structure
    Doru Constantin and Patrick Oswald, Physical Review Letters 85, 4297-4300 (2000).
    preprint
  88. Kinetics of phase ordering of nematic liquid crystals confined in porous media
    Vlad Popa-Nita and Doru Constantin, Physical Review E 60, 1812-1814 (1999).
    preprint

Conference proceedings

  1. Mesostructured silica matrix for irinotecan delivery systems
    S. Nastase, L. Bajenaru, D. Berger, C. Matei, M. G. Moisescu, D. Constantin, T. Savopol, Central European Journal of Chemistry 12, 813-820 (2014).
  2. Coherent X-ray scattering and speckle pattern of solid-supported surfactant bilayers
    Guillaume Brotons, Doru Constantin, Anders Madsen, and Tim Salditt, Physica B 357, 61-65 (2005).

Translations

Liquid crystals: Concepts and Physical Properties Illustrated by Experiments

by Patrick Oswald and Pawel Pieranski (translated from the French by Doru Constantin)

Taylor & Francis; CRC Press 2005

Vol. I : Nematic and Cholesteric Liquid Crystals (648 pages)

Vol. II : Smectic and Columnar Liquid Crystals (712 pages)

French edition

Rheophysics

by Patrick Oswald (translated from the French by Doru Constantin)

Cambridge University Press, 2009.

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